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Gold(I) thioglucoside

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Identification
Molecular formula
C12H16AuO6S
CAS number
.00
IUPAC name
gold(1+);(2R,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)tetrahydropyran-2-thiolate
State
State

At room temperature, Gold(I) thioglucoside is typically a solid. It may be handled as crystals or powder.

Melting point (Celsius)
280.00
Melting point (Kelvin)
553.15
Boiling point (Celsius)
1 090.00
Boiling point (Kelvin)
1 363.15
General information
Molecular weight
353.22g/mol
Molar mass
353.2210g/mol
Density
2.1000g/cm3
Appearence

Gold(I) thioglucoside appears as a solid with a characteristic yellowish or gold-like color. The compound typically forms crystalline solids due to the presence of the gold ion.

Comment on solubility

Solubility of Gold(1+) (2R,3R,4S,5S,6R)-3,4,5-Trihydroxy-6-(hydroxymethyl)tetrahydropyran-2-thiolate

The solubility of the compound gold(1+);(2R,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)tetrahydropyran-2-thiolate with the chemical formula C12H16AuO6S is an intriguing aspect that can be influenced by several factors.

Factors Influencing Solubility

  • Polarity: The presence of hydroxyl groups (-OH) in its structure suggests that this compound may exhibit a degree of polar character, potentially enhancing its solubility in polar solvents like water.
  • Gold Ion Behavior: Gold, particularly in its +1 oxidation state, is known for its unique interactions in aqueous solutions. The solubility of gold thiolates often depends on the thiolate's affinity for metal cations.
  • pH Levels: The solubility can vary with changes in pH, where higher or lower pH levels might alter the ionization status of the hydroxyl and thiol groups.

In general, salt formation, interaction with other solutes, and specific solvent properties can significantly impact solubility outcomes. Thus, while one might expect a reasonable solubility of this compound in polar solvents, empirical testing remains essential for definitive solubility data. Overall, the unique structural features of this compound suggest that its solubility characteristics merit further investigation.

Interesting facts

Interesting Facts about Gold(1+); (2R,3R,4S,5S,6R)-3,4,5-Trihydroxy-6-(hydroxymethyl)tetrahydropyran-2-thiolate

This compound, commonly portrayed in the realm of organometallic chemistry, showcases the unique interplay between gold and organic molecules. Below are some fascinating insights regarding this intriguing compound:

  • Gold as a Metal: Gold has been revered throughout history not just for its aesthetic properties but also for its exceptional conductivity and resistance to oxidation. Its incorporation in compounds may yield unique chemical properties.
  • Thiolate Interaction: The presence of thiolate groups in its structure signifies a strong interaction between the gold ion and sulfur, often leading to increased stability and versatility in various chemical reactions.
  • Stereochemistry: The specified stereochemistry (2R,3R,4S,5S,6R) indicates the compound's chirality. This means it has distinct right and left-handed forms, which can lead to variations in activity and properties.
  • Potential Applications: Compounds like this hold promise in fields such as drug delivery, imaging, and cancer treatment due to the biocompatibility of gold and its chemical reactivity.
  • Natural Derived:** The cyclic structure suggests that it may be modeled after carbohydrate architectures, which can frequently be found in natural products.

Quotes from leading chemists often highlight the intrinsic value of studying compounds rich in transition metals. One famous quote states, “The true science of chemistry lies in its ability to connect the trivial with the monumental.” The exploration of golden compounds promises to bridge both aspects through innovative research and applications.

In conclusion, Gold(1+); (2R,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)tetrahydropyran-2-thiolate offers a remarkable window into the world of organometallic compounds, emphasizing the continual interplay between metal ions and organic frameworks, ultimately fueling advancements in various scientific fields.

Synonyms
AUROTHIOGLUCOSE
Auromyose
Gold thioglucose
Solganal (TN)
Aureotan
Aurothioglucose (USP)
Solganal
Solganol
Aurothioglucose [USP]
AUROTHIOGLUCOSE [MI]
Thioglucosoaurate
AUROTHIOGLUCOSE (IARC)
AUROTHIOGLUCOSE [HSDB]
AUROTHIOGLUCOSE [IARC]
UNII-2P2V9Q0E78
AUROTHIOGLUCOSE [VANDF]
AUROTHIOGLUCOSE (MART.)
AUROTHIOGLUCOSE [MART.]
Thioglucose, Gold
AUROTHIOGLUCOSE (USP-RS)
AUROTHIOGLUCOSE [USP-RS]
AUROTHIOGLUCOSE [WHO-DD]
12192-57-3
2P2V9Q0E78
AUROTHIOGLUCOSE (USP MONOGRAPH)
AUROTHIOGLUCOSE [USP MONOGRAPH]
NSC-759601
(1-D-Glucosylthio)gold
(D-Glucopyranosylthio)gold
1-Aurothio-D-glucopyranose
DTXCID3026013
Goldthioglucose
Aurotan
Thioglucose d'or
(((2R,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl)sulfanyl)gold
{[(2R,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]sulfanyl}gold
Aureotan 100
GOLD, (1-(THIO-.KAPPA.S)-D-GLUCOPYRANOSATO-.KAPPA.O2)
Thioglucose d'or [French]
CCRIS 59
SCHEMBL4666
Gold, (D-glucopyranosylthio)-
CHEBI:2930
HSDB 7174
BDBM496688
EINECS 235-365-7
DB09121
NSC 759601
JOH-UNI-44664832-3
1-Thio-glucopyranose, monogold(1+) salt
1-Thio-D-glucopyranose, monogold(1+) salt
C08193
D00991
Gold, (1-(thio-kappaS)-D-glucopyranosato-kappaO2)-
GOLD, (1-(THIO-KAPPAS)-D-GLUCOPYRANOSATO-KAPPAO2)
235-365-7