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Dichlorodifluoromethane

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Identification
Molecular formula
CCl2F2
CAS number
75-71-8
IUPAC name
dichloro(difluoro)methane
State
State

Gaseous at room temperature but can be condensed into a liquid under pressure. It is part of a class of compounds known as chlorofluorocarbons (CFCs) which have been widely used as refrigerants.

Melting point (Celsius)
-158.00
Melting point (Kelvin)
115.20
Boiling point (Celsius)
-29.80
Boiling point (Kelvin)
243.30
General information
Molecular weight
120.91g/mol
Molar mass
120.9130g/mol
Density
1.4900g/cm3
Appearence

Dichlorodifluoromethane is a colorless gas at room temperature, often stored in steel cylinders. As a compressed liquid, it is colorless and has a slight ether-like odor. It is non-flammable under normal circumstances.

Comment on solubility

Solubility of Dichloro(difluoro)methane

Dichloro(difluoro)methane, also known as R-12 or Freon-12, exhibits unique solubility characteristics in various solvents. Understanding its solubility is crucial for applications in refrigeration and other chemical processes. Here’s a breakdown of its solubility properties:

  • Water Solubility: Dichloro(difluoro)methane is insoluble in water, which is typical for many halogenated compounds. This property affects its use in environments where water interaction is significant.
  • Organic Solvents: It shows good solubility in various organic solvents, such as:
    • Hexane
    • Ethyl acetate
    • Benzene
  • Density Considerations: Due to its higher density compared to water, it tends to settle in mixtures that involve water, further illustrating its insolubility.

Overall, the insolubility of dichloro(difluoro)methane in water and its compatibility with organic solvents make it a significant compound in specialized applications. The distinction of being unable to mix with water while demonstrating solubility in other solvents exemplifies the unique behavior of halogenated hydrocarbons.

Interesting facts

Interesting Facts about Dichloro(difluoro)methane

Dichloro(difluoro)methane, often referred to as Refrigerant 12 or Freon-12, is a unique halocarbon compound that has played a significant role in various industrial applications. Here are some intriguing aspects of this compound:

  • Historical Significance: Introduced in the 1930s, this compound was one of the first chlorofluorocarbons (CFCs) used as a refrigerant. It became popular due to its efficient heat transfer properties and stability under a wide range of conditions.
  • Environmental Impact: While dichloro(difluoro)methane was favored for its performance, its production and usage have been curbed significantly due to its role in ozone depletion. The Montreal Protocol, enacted in 1987, led to a global phase-out of CFCs, including this compound.
  • Chemical Reactions: This compound can undergo various chemical reactions, including nucleophilic substitution and elimination reactions, which makes it a valuable intermediate in organic synthesis.
  • Physical Properties: Dichloro(difluoro)methane is a colorless gas at room temperature and has a pleasant odor, which can mask its hazardous nature. Its low boiling point allows it to vaporize easily, making it effective for cooling applications.
  • Safety Considerations: Despite its effectiveness, safety measures must be adhered to when handling dichloro(difluoro)methane. Exposure can lead to health effects, and it is vital to use appropriate protective equipment and ventilation.
  • Modern Alternatives: With the ongoing evolution in green chemistry, researchers are continuously looking for eco-friendly alternatives to dichloro(difluoro)methane that do not impact the ozone layer or contribute to global warming.

In summary, while dichloro(difluoro)methane has been a staple in refrigeration and air conditioning for decades, the shift towards sustainability and environmental responsibility encourages the search for safer, more environmentally friendly compounds.

Synonyms
DICHLORODIFLUOROMETHANE
75-71-8
Difluorodichloromethane
Genetron 12
Refrigerant 12
Freon 12
Halon
Eskimon 12
Frigen 12
dichloro(difluoro)methane
Electro-CF 12
Chlorofluorocarbon 12
Algofrene type 2
Isotron 2
Propellant 12
Arcton 6
Isotron 12
Arcton 12
Forane 12
Kaiser chemicals 12
Dymel 12
Ledon 12
Isceon 122
Methane, dichlorodifluoro-
Fluorocarbon-12
CFC-12
Freon F-12
Halon 122
Ucon 12
Refrigerant R 12
Ucon 12/halocarbon 12
Dwuchlorodwufluorometan
Freon-12
Fluorocarbon 12
R 12 (refrigerant)
Diclorodifluometano
Halocarbon 12
Rcra waste number U075
Caswell No. 304
FC 12
CCl2F2
Refrigerant R12
CFC 12
FCC 12
FKW 12
Propellent 12
CCRIS 3501
HSDB 139
CF2Cl2
UNII-OFM06SG1KO
F 12
OFM06SG1KO
EINECS 200-893-9
EPA Pesticide Chemical Code 000014
R 12, Refrigerant
AI3-01708
Fron 12
Dichlorodifluoromethane (NF)
Dichlorodifluoromethane [NF]
Chlorofluoromethane (CCl2F2)
METHANE, DICHLORODIFLUORO
DTXSID6020436
EC 200-893-9
R 12
khladon 12
DICHLORODIFLUOROMETHANE (II)
DICHLORODIFLUOROMETHANE [II]
DICHLORODIFLUOROMETHANE (MART.)
DICHLORODIFLUOROMETHANE [MART.]
Diclorodifluometano [Spanish]
Isot ron 2
Dwuchlorodwufluorometan [Polish]
Dichloro-difluoro-methane
UN1028
RCRA waste no. U075
Carbon dichloride difluoride
Sterethox
dichlorodifluormethane
MFCD00000781
R12 [UN1028] [Nonflammable gas]
dichlorodifluoro-methane
dichloro(diluoro)methane
CHLADONE 12
FRIGEN R12
SCHEMBL485
F 12 (HALOCARBON)
CF 12 (HALOCARBON)
DTXCID80436
REFRIGERANT GAS R-12
DWUCHLORODWU-FLUOROMETAN
SCHEMBL9459323
CHEMBL2106634
PXBRQCKWGAHEHS-UHFFFAOYSA-
SDD 100
CHEBI:229860
CF 12
Dichlorodifluoromethane [R12] [UN1028] [Nonflammable gas]
HC 12
DICHLORODIFLUOROMETHANE [MI]
DICHLORODIFLUOROMETHANE [HSDB]
AKOS006228770
DICHLORODIFLUOROMETHANE [VANDF]
UN 1028
DICHLORODIFLUOROMETHANE (CCL2F2)
DICHLORODIFLUOROMETHANE [WHO-DD]
R12 [UN1028] [Nonflammable gas]
InChI=1/CCl2F2/c2-1(3,4)5
F-12
DB-055985
NS00002142
D03789
Dichlorodifluoromethane 100 microg/mL in Methanol
Q423021
Dichlorodifluoromethane 5000 microg/mL in Methanol
Dichlorodifluoromethane [R12] [UN1028] [Nonflammable gas]
200-893-9