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tert-Butyl hydroperoxide

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Identification
Molecular formula
C4H10O2
CAS number
75-91-2
IUPAC name
2-hydroperoxy-2-methyl-propane
State
State

At room temperature, tert-butyl hydroperoxide is a liquid. It can be handled as a liquid under normal laboratory conditions.

Melting point (Celsius)
-4.80
Melting point (Kelvin)
268.35
Boiling point (Celsius)
38.00
Boiling point (Kelvin)
311.15
General information
Molecular weight
90.12g/mol
Molar mass
90.1210g/mol
Density
0.9086g/cm3
Appearence

tert-Butyl hydroperoxide appears as a colorless liquid. It is often noted for its pungent smell and is usually stored with a stabilizer to prevent decomposition.

Comment on solubility

Solubility of 2-hydroperoxy-2-methyl-propane

2-hydroperoxy-2-methyl-propane, a branched organic peroxide, exhibits unique solubility characteristics that are noteworthy for various applications in chemical synthesis and industrial processes. Understanding its solubility can provide valuable insights into its behavior in different environments.

Key Characteristics of Solubility:

  • Polarity: Due to the hydroperoxy functional group, 2-hydroperoxy-2-methyl-propane is relatively polar, which can enhance its solubility in polar solvents.
  • Common Solvents: This compound is expected to be soluble in:
    • Water
    • Alcohols (e.g., methanol, ethanol)
  • Solubility in Non-Polar Solvents: Conversely, its solubility in non-polar solvents (like hexane) may be limited due to its polar nature.

As stated in chemical literature, “the solubility of a compound is crucial in determining its reactivity and stability.” For 2-hydroperoxy-2-methyl-propane, being soluble in polar environments enables the compound to participate effectively in various chemical reactions while also influencing considerations for safe handling and storage.

In summary, the solubility of 2-hydroperoxy-2-methyl-propane showcases an intricate balance between its polar groups and the nature of the solvent, making it an interesting subject for further research and application.

Interesting facts

Interesting Facts about 2-Hydroperoxy-2-Methyl-Propane

2-Hydroperoxy-2-methyl-propane is a fascinating compound noteworthy for its unique structure and applications in various fields of chemistry. Here are some intriguing aspects that highlight its significance:

  • Peroxide Characteristics: This compound contains a peroxide group, which is known for its ability to undergo decomposition, releasing oxygen. This characteristic makes it valuable in oxidation reactions.
  • Radical Initiator: In organic synthesis, 2-hydroperoxy-2-methyl-propane serves as an efficient radical initiator. It decomposes upon heating to generate free radicals, which are essential in numerous polymerization processes.
  • Versatile Reagent: Its reactivity allows it to be used in the synthesis of various organic compounds, making it a versatile reagent in laboratories focused on organic synthesis.
  • Safety Considerations: Due to the instability of peroxides, handling 2-hydroperoxy-2-methyl-propane requires careful consideration of safety protocols to prevent unwanted reactions or explosions.

As noted by chemists in the field, “The utility of 2-hydroperoxy-2-methyl-propane in radical chemistry opens a wide range of possibilities for innovative reactions.” Its role not only in academic research but also in industrial applications underscores the importance of understanding peroxide compounds in chemistry.

Overall, 2-hydroperoxy-2-methyl-propane exemplifies how a seemingly simple molecular structure can have profound implications for both practical applications and theoretical exploration in the realm of chemical science.

Synonyms
TERT-BUTYL HYDROPEROXIDE
75-91-2
TBHP
T-Butyl hydroperoxide
tert-Butylhydroperoxide
2-Hydroperoxy-2-methylpropane
Perbutyl H
t-Butylhydroperoxide
1,1-Dimethylethyl hydroperoxide
Cadox TBH
Hydroperoxide, 1,1-dimethylethyl
Terc. butylhydroperoxid
tert-Butyl hydrogen peroxide
Hydroperoxyde de butyle tertiaire
Hydroperoxide, tert-butyl
Slimicide DE-488
Tertiary butyl hydroperoxide
Trigonox a-75
Trigonox A-W70
TBHP-70
1,1-Dimethylethylhydroperoxide
Tertiary-butyl hydroperoxide
NSC 672
tert-Butyl-hydroperoxide
Caswell No. 130BB
Dimethylethyl hydroperoxide
Perbutyl H 69T
t-BuOOH
Luperox TBH 70X
terc.Butylhydroperoxid
Trigonox A-W 70
tert Butylhydroperoxide
CCRIS 5892
HSDB 837
Kayabutyl H
T-Hydro
EINECS 200-915-7
DE 488
DE-488
UNII-955VYL842B
BRN 1098280
CHEBI:64090
AI3-50541
NSC-672
955VYL842B
Hydroperoxide, 1,1-dimethylethyl-
KAYABUTYL H 70
2-methylpropane-2-peroxol
DTXSID9024693
EC 200-915-7
tert-Butyl Hydroperoxide (70% in Water)
TERT-BUTYL HYDROPEROXIDE (II)
TERT-BUTYL HYDROPEROXIDE [II]
Trigonox A-75 [Czech]
tBOOH
t Butylhydroperoxide
terc.Butylhydroperoxid [Czech]
t Butyl Hydroperoxide
t-BHP
terc. Butylhydroperoxid [Czech]
tert-Butyl Hydroperoxide (5-6 M in Decane)
Hydroperoxide, t-Butyl
tert Butyl Hydroperoxide
tertiary Butylhydroperoxide
Trigonox
Hydroperoxyde de butyle tertiaire [French]
tBuOOH
tert-BuOOH
Ethyldiethylperoxide
tert-Butyldioxidanyl
Perbutyl H 69
Perbutyl H 80
t-butyl-hydroperoxide
terbutyl hydroperoxide
tert-butyhydroperoxide
Terc butylhydroperoxid
tert-C4H9OOH
t-butyl hydrogenperoxide
t-butyl-hydrogenperoxide
tert.-butylhydroperoxide
tert.butyl hydroperoxide
tertiarybutylhydroperoxide
tertbutylhydrogen peroxide
t-butyl hydrogen peroxide
tert.-butyl hydroperoxide
DSSTox_CID_4693
tert-butylhydrogen peroxide
DSSTox_RID_78866
DSSTox_GSID_31209
tertiary butyl hydro peroxide
Hydroperoxide,1-dimethylethyl
Trigonox A-80 (Salt/Mix)
UN 2093 (Salt/Mix)
UN 2094 (Salt/Mix)
USP -800 (Salt/Mix)
CHEMBL348399
DTXCID504693
NSC672
tert-Butyl hydroperoxide (8CI)
tert-Butyl hydroperoxide, >90% with water [Forbidden]
WLN: QOX1&1&1
DTXSID60955527
2-Methyl-prop-2-yl-hydroperoxide
Tox21_200838
Aztec t-butyl Hydroperoxide-70, Aq
MFCD00002130
BUTYL HYDROPEROXIDE (TERTIARY)
TERT-BUTYL HYDROPEROXIDE [MI]
AKOS000121070
TERT-BUTYL HYDROPEROXIDE [HSDB]
tert-Butyl hydroperoxide, 70% in water
NCGC00090725-01
NCGC00090725-02
NCGC00090725-03
NCGC00258392-01
tert-Butyl hydroperoxide aqueous solution
Hydroperoxide, 1,1-dimethylethyl (9CI)
tert-Butyl hydroperoxide, >90% with water
B3153
NS00004543
Q286326
tert-Butyl hydroperoxide solution 70 wt. % in H2O
F1905-8242
200-915-7