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1,7,7-Trimethylnorbornane-2-thione

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Identification
Molecular formula
C11H18S
CAS number
2809-98-5
IUPAC name
1,7,7-trimethylnorbornane-2-thione
State
State

Liquid at room temperature.

Melting point (Celsius)
-45.00
Melting point (Kelvin)
228.15
Boiling point (Celsius)
180.00
Boiling point (Kelvin)
453.15
General information
Molecular weight
168.32g/mol
Molar mass
168.2930g/mol
Density
0.9860g/cm3
Appearence

1,7,7-Trimethylnorbornane-2-thione is often a colorless to pale yellow liquid.

Comment on solubility

Solubility of 1,7,7-trimethylnorbornane-2-thione (C11H18S)

The solubility of 1,7,7-trimethylnorbornane-2-thione presents an intriguing aspect of its chemical behavior. Being a thione, this compound contains the functional group -C(S)-, which can influence its interactions with solvents.

Generally, thiones exhibit varied solubility based on their structure and the nature of the solvent. Here are some key points related to the solubility of 1,7,7-trimethylnorbornane-2-thione:

  • Polarity: This compound is relatively nonpolar due to its hydrocarbon backbone, which reduces its solubility in polar solvents such as water.
  • Solvent Compatibility: It is likely to be soluble in nonpolar solvents like hexane or benzene, where similar hydrophobic interactions can occur.
  • Concentration Effects: In concentrated solutions, the structural integrity of thiones may lead to aggregation, affecting solubility.
  • Temperature Influence: Increasing the temperature could enhance solubility in a given solvent, typically due to increased molecular motion.

As with many organic compounds, experimental data should be consulted for precise solubility values. Remember, "the solvent is key!" Various experimental conditions can yield different solubility behaviors.

In summary, while 1,7,7-trimethylnorbornane-2-thione may show limited solubility in polar solvents, nonpolar solvents may facilitate better dissolution, highlighting the intricate balance between polarity and solubility in chemical compounds.

Interesting facts

Interesting Facts about 1,7,7-Trimethylnorbornane-2-thione

1,7,7-trimethylnorbornane-2-thione is a fascinating compound that belongs to the class of thiones, which are sulfur analogs of ketones. This compound has garnered interest within organic chemistry for several reasons:

  • Structural Complexity: Featuring a bicyclic structure, this compound demonstrates the intricate nature of organic molecules. The presence of multiple methyl groups contributes to its unique three-dimensional conformation.
  • Reactivity: Thiones can participate in a variety of chemical reactions, including nucleophilic additions and cycloadditions. The sulfur atom in this compound can often influence its reactivity in organic synthesis.
  • Applications: Compounds like 1,7,7-trimethylnorbornane-2-thione may be employed in the development of novel materials and could have potential applications in medicinal chemistry or as synthetic intermediates in the preparation of more complex molecules.
  • Synthesis: This compound can be synthesized through various methods, highlighting the toolbox that chemists have at their disposal, including reactions involving thionation or specially designed synthetic pathways.
  • Historical Significance: The study of bicyclic compounds and thiones has played a crucial role in the advancement of organic chemistry. Investigating these types of compounds allows chemists to expand their knowledge of reaction mechanisms and molecular behavior.

In summary, 1,7,7-trimethylnorbornane-2-thione is not only an example of structural diversity in organic chemistry but also serves as a subject of study that enhances our understanding of chemical reactivity and synthesis.

Synonyms
2-Bornanethione
thiocamphor
7519-74-6
1,7,7-Trimethylbicyclo[2.2.1]heptane-2-thione
7WA22E7HFY
RS-THIOCAMPHOR
Bicyclo[2.2.1]heptane-2-thione, 1,7,7-trimethyl-
(+/-)-THIOCAMPHOR
Bicyclo(2.2.1)heptane-2-thione, 1,7,7-trimethyl-
1,7,7-TRIMETHYLBICYCLO(2.2.1)HEPTANE-2-THIONE
UNII-7WA22E7HFY
SCHEMBL4309798
DTXSID80864086
AKOS006228067
NS00120000
T1863
AN-584/40897063
1,7,7-Trimethylbicyclo[2.2.1]heptane-2-thione #